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KMID : 0370219740180030217
Yakhak Hoeji
1974 Volume.18 No. 3 p.217 ~ p.227
Nature of the Hydrogen Chloride Induced Isomers of alpha-Spinasterol
¿ì¿ø½Ä/Woo WS
°­»ï½Ä/Kang SS
Abstract
It was established that alpha-spinasterol (I) was isomerized by hydrogen chloride to a mixture of two isomers. These isomers were separated into each of components and identified as delta8(14),22-stigmastadienol (III) and delta14,22-stigmastadienol (IV), respectively. The mass spectra of these compounds were found to be particularly suitable to identify the position of nuclear double bond of sterols possessing 22 : 23-double bond in side chain.
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